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Summary:  Ambipolar transport has been realised in blends of the molecular hole conductor Cu‐phthalocyanine (CuPc) and the electron conducting fullerene C 60 . Charge carrier mobilities and the occupied electronic levels have been analyzed as a function of the mixing ratio using field‐effect transistor measurements and photoelectron spectroscopy. These results are discussed in the context of photovoltaic cells based on these materials.

Ambipolar Blends of Cu‐Phthalocyanine and Fullerene: Charge Carrier Mobility, Electronic Structure and their Implications for Solar Cell Applications