Premium
Evaluation of bonded layer disorder from thermodynamic behavior of methylaminopropyl groups immobilized on sio 2
Author(s) -
Zaitsev V. N.,
Oleynik V. D.,
Budarin V. L.
Publication year - 1998
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19981360114
Subject(s) - covalent bond , proton , materials science , layer (electronics) , chemical engineering , polymer chemistry , chemistry , composite material , organic chemistry , physics , quantum mechanics , engineering
Abstract Thermodynamic characteristics of reaction between proton and methylaminopropyl groups that are covalently bonded to silica gel surface were calculated. First evidence of short‐distance interaction between neighboring bonded amines was obtained. Addition of the first proton does not destroy such interaction. Second proton promotes significant geometry changing.