Disproportionation reactions between alkyl and fluoroalkyl radicals. II. Fluoro‐ and trifluoromethyl with ethyl radicals

Cross‐disproportionation/combination ratios for CFH 2 and CF 3 with C 2 H 5 radicals have been determined to be Δ = 0.032 ± 0.012 and δ = 0.098 ± 0.020, respectively, over the temperature range 25–75°C. For the pathway that yields CFH and C 2 H 6 , δ = 0.020 ± 0.005 at 25°C.