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Disproportionation reactions between alkyl and fluoroalkyl radicals. II. Fluoro‐ and trifluoromethyl with ethyl radicals
Author(s) -
Pritchard G. O.,
Nilsson W. B.,
Marchant P. E.,
Case L. C.,
Parmer J. F.,
Youngs R. F.
Publication year - 1984
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550160109
Subject(s) - disproportionation , chemistry , radical , radical disproportionation , trifluoromethyl , alkyl , photochemistry , medicinal chemistry , organic chemistry , catalysis
Cross‐disproportionation/combination ratios for CFH 2 and CF 3 with C 2 H 5 radicals have been determined to be Δ = 0.032 ± 0.012 and δ = 0.098 ± 0.020, respectively, over the temperature range 25–75°C. For the pathway that yields CFH and C 2 H 6 , δ = 0.020 ± 0.005 at 25°C.
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