Vibrational spectra and structures of fluoroalkyl and fluoroaryl compounds of tellurium: Te 2 (CF 3 ) 2 , Te 2 (C 6 F 5 ) 2  and Te(C 6 F 5 ) 2 | Zendy

Hoge B. | Zendy; Naumann D. | Zendy; Pohl H. | Zendy; Shamir J. | Zendy

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Vibrational spectra and structures of fluoroalkyl and fluoroaryl compounds of tellurium: Te 2 (CF 3 ) 2 , Te 2 (C 6 F 5 ) 2 and Te(C 6 F 5 ) 2

Author(s) -

Hoge B.,

Naumann D.,

Pohl H.,

Shamir J.

Publication year - 2003

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.936

Subject(s) - raman spectroscopy , tellurium , chemistry , crystallography , infrared , infrared spectroscopy , spectral line , analytical chemistry (journal) , stereochemistry , physics , inorganic chemistry , optics , astronomy , organic chemistry , chromatography

Raman and infrared spectra of Te 2 (CF 3 ) 2 , Te 2 (C 6 F 5 ) 2 and Te(C 6 F 5 ) 2 were studied and their structures determined. Polarization measurements of Raman lines of the neat liquid Te 2 (CF 3 ) 2 and of CCl 4 solutions of Te 2 (C 6 F 5 ) 2 and Te(C 6 F 5 ) 2 were also performed, allowing the assignment of symmetric and asymmetric vibrations. The observed coinciding wavenumbers supported the skeletal C 2 symmetry structure for the Te 2 R 2 compounds. Copyright © 2002 John Wiley & Sons, Ltd.

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