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The ν 5 Raman band of CH 3 CD 3
Author(s) -
Jensen Per,
Brodersen Svend
Publication year - 1982
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250120318
Subject(s) - raman spectroscopy , wavenumber , resolution (logic) , g band , magnitude (astronomy) , physics , nuclear magnetic resonance , optics , molecular physics , chemistry , analytical chemistry (journal) , materials science , computer science , chromatography , astrophysics , artificial intelligence
Abstract The ν 5 Raman band of CH 3 CD 3 was photographed with a resolution of about 0.4 cm −1 and analysed by an iterative method, in which the peak wavenumbers of the observed and computed contours are compared directly. Precise values for ν 0 and Δ B were obtained, whereas it only could be shown that Δ A is an order of magnitude smaller than Δ B . Some basic problems of the method of analysis are discussed.