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The pure‐rotational Raman spectrum of disilane
Author(s) -
Shotton K. C.,
Lee A. G.,
Jones W. J.
Publication year - 1973
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250010304
Subject(s) - disilane , raman spectroscopy , chemistry , analytical chemistry (journal) , physics , organic chemistry , optics , silicon
Abstract From a study of the rotational Raman spectra of disilane and hexadeutero‐disilane the following rotational constants were determined: for Si 2 H 6 , B 0 = 0.16998 ± 0.00003 cm −1 ; for Si 2 D 6 , B 0 = 0.13796 ± 0.00004 cm −1 . The rotational constants were used to provide values for the internuclear distances in these modecules.