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Ein Methanoditetrazolo‐[1,3,6,8]tetrazecin aus 5‐(Chlormethyl)tetrazol und Hexamethylentetramin
Author(s) -
Moderhack Dietrich,
Goos KarlHeinz,
Preu Lutz
Publication year - 1989
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198919890214
Subject(s) - hexamethylenetetramine , chemistry , tetrazole , formaldehyde , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry
A Methanoditetrazolo‐[1,3,6,8]tetrazecine from 5‐(Chloro‐methyl)tetrazole and Hexamethylenetetramine In contrast to N ‐substituted 5‐(chloromethyl)tetrazoles ( 1 ; Ralkyl, aryl), the parent compound 1 (RH) reacts with hexamethylenetetramine to give the methanoditetrazolo‐[1,3,6,8]tetrazecine 4 , a rather unusual system. This compound which is also produced on reaction of 7 with formaldehyde occurs in the (6 RS ,13 RS ) form.