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Es werden Herstellung, Strukturaufklärung und Eigenschaften des durch doppelte Cycloaddition von Cyclohexanon an Carbonyldiisocyanat gefundenen neuen Heterocyclensystems Cyclohexan‐1‐spiro‐9 ′‐[ 1,3,5]oxadiazino[3,4‐e][l,3,5]dioxazin‐5′‐spiro‐1 ”‐cyclohexan‐2′,7′‐ dions (5) beschrieben.