Stereochemistry from X‐Ray Diffraction Studies of Three Palladium(II) Complexes with Terdentate Chelating Amines | Zendy

Manohar Hattikudur | Zendy; Schwarzenbach Dieter | Zendy

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Stereochemistry from X‐Ray Diffraction Studies of Three Palladium(II) Complexes with Terdentate Chelating Amines

Author(s) -

Manohar Hattikudur,

Schwarzenbach Dieter

Publication year - 1974

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19740570303

Subject(s) - chemistry , palladium , chelation , dapi , protonation , crystal structure , metal , x ray crystallography , crystallography , diffraction , stereochemistry , ion , inorganic chemistry , organic chemistry , catalysis , apoptosis , biochemistry , physics , optics

X‐ray crystal structure analysis of three Pd(II) complexes with cis ‐3,5‐diaminopiperidine (DAPI) shows that the metal ion has a square planar coordination. The DAPI groups are trans in the protonated and mixed complexes. Most surprisingly, the unprotonated complex has a basket‐like structure with the DAPI groups cis .

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