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The Diphosphorus Complex [Cp 2 Mo 2 (CO) 4 (η 2 ‐P 2 )] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers
Author(s) -
Moussa Mehdi Elsayed,
Attenberger Bianca,
Fleischmann Martin,
Schreiner Andrea,
Scheer Manfred
Publication year - 2016
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201600895
Subject(s) - chemistry , group 2 organometallic chemistry , polymer , molecule , block (permutation group theory) , hybrid material , derivative (finance) , component (thermodynamics) , ion , crystallography , polymer chemistry , stereochemistry , inorganic chemistry , organic chemistry , financial economics , physics , geometry , mathematics , economics , thermodynamics
The three‐component reaction of the tetrahedral diphosphorus complex [Cp 2 Mo 2 (CO) 4 (η 2 ‐P 2 )] ( 1 ), with Ag[BF 4 ] ( 2 ) in the presence of 2,2′‐bipyrimidine ( 3 ) leads to the formation of the two novel two‐dimensional networks 4 and 5 . Compound 4 is a new two‐dimensional organometallic‐organic hybrid polymer, while derivative 5 represents a unique two‐dimensional organometallic‐inorganic‐organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two‐component reactions with organic molecules in addition of metal ions.