Unimolecular Decay of Metastable Cluster Anions: (O 2 )  N   − * → (O 2 )       N‐1    −     + O 2 | Zendy

Scheier P. | Zendy; Märk T. D. | Zendy

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Unimolecular Decay of Metastable Cluster Anions: (O 2 ) N − * → (O 2 ) N‐1 − + O 2

Author(s) -

Scheier P.,

Märk T. D.

Publication year - 1990

Publication title -

contributions to plasma physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.531

H-Index - 47

eISSN - 1521-3986

pISSN - 0863-1042

DOI - 10.1002/ctpp.2150300606

Subject(s) - metastability , excited state , cluster (spacecraft) , dissociation (chemistry) , atomic physics , physics , ion , crystallography , materials science , chemistry , quantum mechanics , computer science , programming language

Unimolecular dissociation of metastable excited states of (O 2 ) n − * into (O 2 ) n‐1 −cluster anions has been detected and studied quantitatively for n in the range of 13 to 22. The apparent metastable (decay rates determined increase with cluster size in from ∼ 5000 s −1 (for n = 13) up to ∼ 8500 s −1 for n = 22).

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