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Mixed‐Halide Double Perovskite Cs 2 AgBiX 6 (X=Br, I) with Tunable Optical Properties via Anion Exchange
Author(s) -
Wu Hua,
Erbing Axel,
Johansson Malin B.,
Wang Junxin,
Kamal Chinnathambi,
Odelius Michael,
Johansson Erik M. J.
Publication year - 2021
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202101146
Subject(s) - halide , iodide , perovskite (structure) , chemistry , inorganic chemistry , ion exchange , band gap , bromide , dissolution , ion , materials science , crystallography , optoelectronics , organic chemistry
Lead‐free double perovskites, A 2 M + M ′3+ X 6 , are considered as promising alternatives to lead‐halide perovskites, in optoelectronics applications. Although iodide (I) and bromide (Br) mixing is a versatile tool for bandgap tuning in lead perovskites, similar mixed I/Br double perovskite films have not been reported in double perovskites, which may be due to the large activation energy for ion migration. In this work, mixed Br/I double perovskites were realized utilizing an anion exchange method starting from Cs 2 AgBiBr 6 solid thin‐films with large grain‐size. The optical and structural properties were studied experimentally and theoretically. Importantly, the halide exchange mechanism was investigated. Hydroiodic acid was the key factor to facilitate the halide exchange reaction, through a dissolution–recrystallization process. In addition, the common organic iodide salts could successfully perform halide‐exchange while retaining high mixed‐halide phase stability and strong light absorption capability.