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Integrated Co‐Electrolysis and Syngas Methanation for the Direct Production of Synthetic Natural Gas from CO 2 and H 2 O
Author(s) -
Mebrahtu Chalachew,
Nohl Markus,
Dittrich Lucy,
Foit Severin R.,
Haart L. G. J. Bert,
Eichel RüdigerA.,
Palkovits Regina
Publication year - 2021
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202002904
Subject(s) - syngas , methanation , substitute natural gas , electrolysis , catalysis , chemical engineering , water gas shift reaction , power to gas , natural gas , chemistry , synthetic fuel , materials science , organic chemistry , electrode , engineering , electrolyte
The concept of an integrated power‐to‐gas (P2G) process was demonstrated for renewable energy storage by converting renewable electrical energy to synthetic fuels. Such a dynamically integrated process enables direct production of synthetic natural gas (SNG) from CO 2 and H 2 O. The produced SNG can be stored or directly injected into the existing natural gas network. To study process integration, operating parameters of the high‐temperature solid oxide electrolysis cell (SOEC) producing syngas (H 2 +CO) mixtures through co‐electrolysis and a fixed bed reactor for syngas methanation of such gas mixtures were first optimized individually. Reactor design, operating conditions, and enhanced SNG selectivity were the main targets of the study. SOEC experiments were performed on state‐of‐the‐art button cells. Varying operating conditions (temperature, flow rate, gas mixture and current density) emphasized the capability of the system to produce tailor‐made syngas mixtures for downstream methanation. Catalytic syngas methanation was performed using hydrotalcite‐derived 20 %Ni‐2 %Fe/(Mg,Al)O x catalyst and commercial methanation catalyst (Ni/Al 2 O 3 ) as reference. Despite water in the feed mixture, SNG with high selectivity (≥90 %) was produced at 300 °C and atmospheric pressure. An adequate rate of syngas conversion was obtained with H 2 O contents up to 30 %, decreasing significantly for 50 % H 2 O in the feed. Compared to the commercial catalyst, 20 %Ni‐2 %Fe/(Mg,Al)O x enabled a higher rate of CO x conversion.