Electron Paramagnetic Resonance of VO 2+  in M 2 Zn(SeO 4 ) 2  · 6H 2 O(M=K, Rb) Single Crystals | Zendy

Yadav S. K. | Zendy; Jain V. K. | Zendy

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Electron Paramagnetic Resonance of VO 2+ in M 2 Zn(SeO 4 ) 2 · 6H 2 O(M=K, Rb) Single Crystals

Author(s) -

Yadav S. K.,

Jain V. K.

Publication year - 1992

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.2170270723

Subject(s) - electron paramagnetic resonance , crystallography , single crystal , chemistry , spectral line , inorganic compound , crystal structure , analytical chemistry (journal) , materials science , nuclear magnetic resonance , physics , astronomy , organic chemistry , chromatography

The EPR spectrum of VO 2+ has been studied in single crystals of K 2 Zn(SeO 4 ) 2 · 6H 2 O and Rb 2 Zn(SeO 4 ) 2 ∼ 6H 2 O at ∼9.45 GHz. VO 2+ substitutes for Zn 2+ have preferential orientations in the lattice. The V = O of the intense vanadyl center is nearly along the longest ZnH 2 O direction. Spin‐Hamiltonian parameters have been evaluated from single crystal as well as from powder spectra.

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