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Thermoluminescence and the emission of γ‐irradiated BaFCl:Eu 2+  has been studied. A well defined glow peak at 400 K and a shoulder at 480 K are obtained in addition to those obtained as in undoped BaFCl. Thermoluminescence emission has shown a band at about 390 ∼ 400 nm. Additional glow peaks have been attributed to the luminescence centers as caused by europium impurity.