An Approach to Chemical Reaction Engineering and Process Intensification for the Lean Aqueous Hydroformylation Using a Jet Loop Reactor | Zendy

Esteban Jesús | Zendy; Warmeling Helge | Zendy; Vorholt Andreas J. | Zendy

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An Approach to Chemical Reaction Engineering and Process Intensification for the Lean Aqueous Hydroformylation Using a Jet Loop Reactor

Author(s) -

Esteban Jesús,

Warmeling Helge,

Vorholt Andreas J.

Publication year - 2019

Publication title -

chemie ingenieur technik

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.365

H-Index - 36

eISSN - 1522-2640

pISSN - 0009-286X

DOI - 10.1002/cite.201800137

Subject(s) - hydroformylation , tppts , catalysis , aqueous solution , chemistry , aqueous two phase system , chemical engineering , injector , reactivity (psychology) , solvent , organic chemistry , thermodynamics , engineering , rhodium , physics , medicine , alternative medicine , pathology

The biphasic hydroformylation of 1‐octene using a lean aqueous phase as solvent phase for catalyst recycling is discussed here. The gas‐liquid‐liquid reaction was homogeneously catalyzed by industrial standard catalytic system with [Rh(cod)Cl] 2 as precursor and TPPTS as ligand. This work summarizes investigations addressing different aspects of the reaction, where a procedural approach was followed to gain understanding of its nature, kinetics and interphase reactivity. Finally, the application of the jet loop reactor is analyzed as a means to intensify the reaction.

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