English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Open

Presents the pdf analysis as premium feature

PDF Analysis

Insights

Presents the summarisation as premium feature

Summarisation

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

The electron‐rich Pt complex [Pt(IMes) 2 ] (IMes: [1,3‐bis(2,4,6‐trimethylphenyl)‐2‐imidazolinylidine]) can be used as precursor for the syntheses of a variety of fluorido ligand containing compounds. The sulfur fluoride SF 4  undergoes a rapid oxidative addition at Pt 0  to yield  trans ‐[Pt(F)(SF 3 )(IMes) 2 ]. A photolytic reaction of SF 6  at [Pt(IMes) 2 ] in the presence of IMes gave the fluorido complexes  trans ‐[Pt(F) 2 (IMes) 2 ] and  trans ‐[Pt(F)(SF 3 )(IMes) 2 ] along with  trans ‐[Pt(F)(SOF)(IMes) 2 ] and  trans ‐[Pt(F)(IMes’)(IMes)] (IMes’: cyclometalated IMes ligand), the latter being products produced by reaction with adventitious water.  trans ‐[Pt(F)(SOF)(IMes) 2 ] and  trans ‐[Pt(F) 2 (IMes) 2 ] were synthesized independently by treatment of [Pt(IMes) 2 ] with SOF 2  or XeF 2 . A reaction of [Pt(IMes) 2 ] with a HF source gave  trans ‐[Pt(H)(F)(IMes) 2 ], and an intermediate bifluorido complex  trans ‐[Pt(H)(FHF)(IMes) 2 ] was identified. Compound  trans ‐[Pt(H)(F)(IMes) 2 ] converts in the presence of CsF into  trans ‐[Pt(F)(IMes’)(IMes)].

Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF 3 , S(=O)F and Fluorido Complexes