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A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
Author(s) -
Kervarec MaëvaCharlotte,
Kemnitz Erhard,
Scholz Gudrun,
Rudić Svemir,
Braun Thomas,
Jäger Christian,
Michalchuk Adam A. L.,
Emmerling Franziska
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202001627
Subject(s) - lewis acids and bases , anhydrous , aluminium , reactivity (psychology) , catalysis , chemistry , characterization (materials science) , inorganic chemistry , nuclear chemistry , materials science , organic chemistry , nanotechnology , medicine , alternative medicine , pathology
The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF‐loaded ACF towards the hydrofluorination of alkynes was studied.