Premium
Visible‐Light Controlled Divergent Catalysis Using a Bench‐Stable Cobalt(I) Hydride Complex
Author(s) -
Bergamaschi Enrico,
Beltran Frédéric,
Teskey Christopher J.
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202000410
Subject(s) - catalysis , olefin fiber , hydroboration , hydride , cobalt , visible spectrum , transition metal , chemistry , photochemistry , combinatorial chemistry , nanotechnology , materials science , metal , inorganic chemistry , organic chemistry , optoelectronics
While the use of visible light in conjunction with transition metal catalysis offers powerful opportunities to switch between on/‐off states of catalytic activity, the next frontier would be the ability to switch the actual function of the catalyst and resulting products. Here we report such an example of multi‐dimensional catalysis. Featuring an easily prepared, bench‐stable cobalt(I) hydride complex in conjunction with pinacolborane, we can switch the reaction outcome between two widely employed transformations, olefin migration and hydroboration, with visible light as the trigger.