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Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO) 6
Author(s) -
Bonn Pit,
Bolm Carsten,
Hernández José G.
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201904528
Subject(s) - carbon monoxide , catalysis , palladium , carbonylation , molybdenum , chemistry , aryl , monoxide , inorganic chemistry , organic chemistry , alkyl
Esters and amides were mechanochemically prepared by palladium‐catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real‐time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO) 6 to the active catalytic system without significant release of molecular carbon monoxide.