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Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels–Alder Reactions
Author(s) -
Sen Rickdeb,
Gahtory Digvijay,
Escorihuela Jorge,
Firet Judith,
Pujari Sidharam P.,
Zuilhof Han
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201703103
Subject(s) - surface modification , kinetics , substrate (aquarium) , inverse , chemistry , diels–alder reaction , organic chemistry , catalysis , physics , biology , mathematics , ecology , geometry , quantum mechanics
Abstract Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels–Alder (IEDDA) reactions represent a promising metal‐free candidate. Herein, we reveal quantitative surface functionalization within 15 min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained by surface‐bound mass spectrometry (DART‐HRMS).