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CF Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate, and Subsequent Fluoride Transfer Reactions
Author(s) -
Ung Gaël,
Bertrand Guy
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202292
Subject(s) - dithiocarbamate , anhydrous , electrophile , chemistry , fluoride , reagent , adduct , ionic bonding , medicinal chemistry , organic chemistry , inorganic chemistry , ion , catalysis
F‐act finding mission : Selective activation of the para CF bonds of perfluorinated aromatic derivatives was achieved with a simple ethynyl dithiocarbamate. The resulting adducts can be used as non‐ionic, anhydrous fluoride transfer reagents towards various electrophiles (see scheme).