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Radical control:  A single glutamate residue (E287) in the coenzyme B 12 ‐dependent ethanolamine ammonia lyase is pivotal to generating high‐energy radical intermediates during catalysis and then controlling the radical chemistry. Using a dynamic, electrostatic mechanism, it helps to guide the radical intermediates towards the desired end by preventing side reactions.

Dynamic, Electrostatic Model for the Generation and Control of High‐Energy Radical Intermediates by a Coenzyme B 12 ‐Dependent Enzyme