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Organoamido‐ and Aryloxo‐lanthanoids, 14 . Organometallic Compounds of the Lanthanoids, 106 . Synthesis and Characterisation of Complexes of Lanthanoid Pyrazolates with 1,2‐Dimethoxyethane and the X‐Ray Structures of (1,2‐Dimethoxyethane‐ O 1 : O 2 )(1,2‐dimethoxyethane‐ O 1 )tris(3,5‐diphenylpyrazolato)erbium(III) and catena ‐Poly[tris(3,5‐di‐ tert ‐butylpyrazolato)‐μ‐(1,2‐dimethoxyethane‐ O 1 : O 2 )‐neodymium(III)]
Author(s) -
Cosgriff Joanna E.,
Deacon Glen B.,
Fallon Gary D.,
Gatehouse Bryan M.,
Schumann Herbert,
Weimann Roman
Publication year - 1996
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19961290812
Subject(s) - dimethoxyethane , chemistry , lanthanide , crystallography , trigonal bipyramidal molecular geometry , chelation , pyrazole , stereochemistry , medicinal chemistry , crystal structure , inorganic chemistry , organic chemistry , ion , electrode , electrolyte
Abstract The complexes [Ln(Ph 2 pz) 3 (DME) 2 ] and [Ln( t Bu 2 pz) 3 (DME)] (Ln = La, Nd, Er; Ph 2 pzH = 3,5‐diphenylpyrazole; t Bu 2 pzH = 3,5‐di‐ tert ‐butylpyrazole; DME = 1,2‐dimethoxyethane) have been prepared by reaction of the lanthanoid metal with bis(pentafluorophenyl)mercury and the pyrazole in DME. The molecular structures of [Er(Ph 2 pz) 3 (DME) 2 ] ( 3 ) and [Nd( t Bu 2 pz) 3 (DME)] ∞ ( 5 ) have been determined by X‐ray diffraction. Complex 3 has nine‐coordinate Er with three chelating Ph 2 pz ligands and one chelating and one η 1 ‐bound DME. There is a trigonal prismatic arrangement of the oxygen donors and the centres of the N – N bonds. 5 was found to be a linear polymer with transoid DME ligands bridging Nd( t Bu 2 pz) 3 units in a novel manner. The centres of the N – N bonds (which are essentially coplanar with Nd), and the oxygen donor atoms adopt an arrangement intermediate between trigonal‐bipyramidal and square‐pyramidal [O – Nd – O 153.5(2)°].