Complexes with sterically demanding ligands, XVI. An unexpected coupling of trimethylsilyl‐substituted cyclopentadienide anion by ferric chloride | Zendy

Okuda Jun | Zendy; Herdtweck Eberhardt | Zendy; Zeller Edgar M. | Zendy

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Complexes with sterically demanding ligands, XVI. An unexpected coupling of trimethylsilyl‐substituted cyclopentadienide anion by ferric chloride

Author(s) -

Okuda Jun,

Herdtweck Eberhardt,

Zeller Edgar M.

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240716

Subject(s) - chemistry , trimethylsilyl , ferric , steric effects , chloride , medicinal chemistry , derivative (finance) , tris , trimethylsilyl chloride , ion , polymer chemistry , organic chemistry , catalysis , biochemistry , financial economics , economics

Reaction of 1,2,4‐tris(trimethylsilyl)cyclopentadienyllithium with ferric chloride in THF at ‐95°C leads to the formation of a thermally sensitive iron(III) complex which decomposes to the new dihydrofulvalene derivative 3,7‐dihydro‐1,3,3,5,7,7‐hexakis(trimethylsilyl)fulvalene ( 1 ).

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