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Anchimer beschleunigte Homolysen, V. Thermische und Fluoridionen‐katalysierte Umlagerungen von Benzyl)‐[9‐(trimethylgermyl)‐9‐fluorenyl]‐ether
Author(s) -
Reetz Manfred T.,
Maaroufi Azzedine,
Greif Norbert
Publication year - 1980
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19801130240
Subject(s) - chemistry , homolysis , ether , medicinal chemistry , fluoride , ion , polymer chemistry , photochemistry , organic chemistry , inorganic chemistry , radical
Anchimerically Enhanced Homolyses, V. Fluoride Ion Catalysed Rearrangements of Benzyl 9‐(Trimethylgermyl)‐9‐fluorenyl Ether The thermal rearrangement (homolysis) of the germanium compound 1d into 4d is considerably slower than that of the analogous Si compound 1c . Thus, a correlation is suggested between the velocity of the rearrangement and the strength of the new bond to oxygen. The rearrangement 1d → 4d is also induced by fluoride ions at room temperature.