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Meeting the Challenge of Intermolecular Gold(I)‐Catalyzed Cycloadditions of Alkynes and Allenes
Author(s) -
Muratore Michael E.,
Homs Anna,
Obradors Carla,
Echavarren Antonio M.
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201402395
Subject(s) - intermolecular force , intramolecular force , chemistry , catalysis , cycloaddition , allene , computational chemistry , stereochemistry , organic chemistry , molecule
The development of gold(I)‐catalyzed intermolecular carbo‐ and hetero‐cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes.