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Chiral self‐sorting is intricately connected to the complicated chiral processes observed in nature and no artificial systems of comparably complexity have been generated by chemists. However, only a few examples of purely organic molecules have been reported so far, where the self‐sorting process could be controlled. Herein, we describe the chiral self‐sorting of large cubic [8+12] salicylimine cage compounds based on a chiral TBTQ precursor. Out of 23 possible cage isomers only the enantiopure and a  meso  cage were observed to be formed, which have been unambiguously characterized by single crystal X‐ray diffraction. Furthermore, by careful choice of solvent the formation of  meso  cage could be controlled. With internal diameters of  d  in =3.3–3.5 nm these cages are among the largest organic cage compounds characterized and show very high specific surface areas up to approx. 1500 m 2  g −1  after desolvation.

Chiral Self‐sorting of Giant Cubic [8+12] Salicylimine Cage Compounds