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Molecular Semiconductor Surfactants with Fullerenol Heads and Colored Tails for Carbon Dioxide Photoconversion
Author(s) -
Kunkel Marius,
Sutter Sebastian,
Polarz Sebastian
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201905410
Subject(s) - bilayer , photochemistry , amphiphile , chemistry , membrane , pulmonary surfactant , chemical engineering , nanotechnology , materials science , organic chemistry , biochemistry , engineering , copolymer , polymer
Abstract The leaf is a prime example of a material converting waste (CO 2 ) into value with maximum sustainability. As the most important constituent, it contains the coupled photosystems II and I, which are imbedded in the cellular membrane of the chloroplasts. Can key functions of the leaf be packed into soap? We present next‐generation surfactants that self‐assemble into bilayer vesicles (similar to the cellular membrane), are able to absorb photons of two different visible wavelengths, and exchange excited charge carriers (similar to the photosystems), followed by conversion of CO 2 (in analogy to the leaf). The amphiphiles contain five dye molecules as the hydrophobic entity attached exclusively to one hemisphere of a polyhydroxylated fullerene (Janus‐type). We herein report on their surfactant, optical, electronic, and catalytic properties. Photons absorbed by the dyes are transferred to the fullerenol head, where they can react with different species such as CO 2 to give formic acid.