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A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
Author(s) -
Magnin Guillaume,
Clifton Jamie,
Schoenebeck Franziska
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201903765
Subject(s) - conjugated system , catalysis , monomer , palladium , polymer , polymerization , reagent , dimer , materials science , reactivity (psychology) , polymer chemistry , nanotechnology , chemical engineering , combinatorial chemistry , chemistry , organic chemistry , medicine , alternative medicine , pathology , engineering
While current M 0 /M II based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd I catalyst. The method is operationally simple, robust and tolerant to air.