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Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
Author(s) -
Kindt Stephanie,
Wicht Karina,
Heinrich Markus R.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201601656
Subject(s) - chemistry , crossover , polar , metal , radical , combinatorial chemistry , polymer chemistry , organic chemistry , photochemistry , physics , astronomy , artificial intelligence , computer science
The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be extended to carboetherification as well as to a two‐step, metal‐free variant of the Meerwein arylation leading to stilbenes.