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A nickel(II) porphyrin  Ni‐P  (P=porphyrin) bearing four  meso ‐C 6 F 5  groups to improve solubility and activity was used to explore different hydrogen‐evolution‐reaction (HER) mechanisms. Doubly reduced  Ni‐P  ([ Ni‐P ] 2− ) was involved in H 2  production from acetic acid, whereas a singly reduced species ([ Ni‐P ] − ) initiated HER with stronger trifluoroacetic acid (TFA). High activity and stability of  Ni‐P  were observed in catalysis, with a remarkable  i  c / i  p  value of 77 with TFA at a scan rate of 100 mV s −1  and 20 °C. Electrochemical, stopped‐flow, and theoretical studies indicated that a hydride species [H‐ Ni‐P ] is formed by oxidative protonation of [ Ni‐P ] − . Subsequent rapid bimetallic homolysis to give H 2  and  Ni‐P  is probably involved in the catalytic cycle. HER cycling through this one‐electron‐reduction and homolysis mechanism has been proposed previously but rarely validated. The present results could thus have broad implications for the design of new exquisite cycles for H 2  generation.

Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen‐Evolution Reaction