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Domino Catalysis: Palladium‐Catalyzed Carbonylation of Allylic Alcohols to β,γ‐Unsaturated Esters
Author(s) -
Liu Qiang,
Wu Lipeng,
Jiao Haijun,
Fang Xianjie,
Jackstell Ralf,
Beller Matthias
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303850
Subject(s) - carbonylation , catalysis , allylic rearrangement , domino , chemistry , palladium , organic chemistry , combinatorial chemistry , carbon monoxide
Make it green : The Pd‐catalyzed carbonylation of allylic alcohols with aliphatic alcohols represents a cost‐effective, salt‐free, and atom‐economic carbonylation process generating water as the sole by‐product. Mechanistic studies uncovered a new domino CO coupling/carbonylation reaction pathway.
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