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Rhodium‐Catalyzed Cascade Reactions of Dienynes Leading to Substituted Dihydronaphthalenes and Naphthalenes
Author(s) -
Okazaki Eri,
Okamoto Ryuichi,
Shibata Yu,
Noguchi Keiichi,
Tanaka Ken
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202125
Subject(s) - cycloisomerization , cascade , rhodium , catalysis , cationic polymerization , chemistry , enantioselective synthesis , combinatorial chemistry , organic chemistry , chromatography
Five in one : Catalytic cascade reactions of dienynes catalyzed by cationic rhodium(I)–binap complexes lead to the formation of 1,2‐dihydronaphthalenes, naphthalenes, and 1,4‐dihydronaphthalenes. These cascade reactions involve up to five fundamentally different transformations, including the catalytic enantioselective carboformylation of alkenes with aldehydes or the cycloisomerization of enallenes.