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In a flash : The total synthesis of transtaganolide and basiliolide natural products is achieved in three steps from achiral, monocyclic esters (see scheme). Featured in the syntheses are an Ireland‐Claisen/Diels–Alder cascade and a novel methoxyacetylide coupling/cyclization sequence.

angewandte chemie international edition

A General Approach to the Basiliolide/Transtaganolide Natural Products: Total Syntheses of Basiliolide B,  epi ‐8‐Basiliolide B, Transtaganolide C, and Transtaganolide D