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Halogen‐Bridged Pt II /Pt IV Mixed‐Valence Ladder Compounds
Author(s) -
Kawakami Daisuke,
Yamashita Masahiro,
Matsunaga Satoshi,
Takaishi Shinya,
Kajiwara Takashi,
Miyasaka Hitoshi,
Sugiura Kenichi,
Matsuzaki Hiroyuki,
Okamoto Hiroshi,
Wakabayashi Yusuke,
Sawa Hiroshi
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602987
Subject(s) - halogen , halide , valence (chemistry) , chemistry , crystallography , ion , bridging (networking) , band gap , stereochemistry , inorganic chemistry , physics , condensed matter physics , computer science , organic chemistry , computer network , alkyl
Chutes and … Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen‐bridged Pt II /Pt IV mixed‐valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled.