Premium
Synthesis and Structure of Bimetallic η 4 ,η 6 ‐Naphthalene Complexes Containing a MnMn Moiety Bonded in a syn ‐Facial Manner: A General Route to Homo‐ and Heteronuclear Bimetallic Complexes of Polyarenes
Author(s) -
Sun Shouheng,
Dullaghan Conor A.,
Carpenter Gene B.,
Rieger Anne L.,
Rieger Philip H.,
Sweigart Dwight A.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199525401
Subject(s) - bimetallic strip , moiety , heteronuclear molecule , manganese , naphthalene , crystallography , reagent , chemistry , ring (chemistry) , stereochemistry , nuclear magnetic resonance spectroscopy , catalysis , organic chemistry
The ability of [(polyarene)Mn(CO) 3 ] + to function as a facile manganese tricarbonyl transfer reagent is the basis for a general synthetic route to homo‐ and heteronuclear bimetallic complexes of naphthalenes and related fused ring systems such as 1,2 , and 3 .