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The title compound 2 is characterized by many interesting features: 2  is the first dilithiomethane stabilized by two boryl substituents; NMR and X‐ray data establish its 1,3‐diborataallene structure. In contrast to known dilithio‐methane derivatives, which are aggregated,  2  is monomeric (R = 2,4,6‐Me 3 C 6 H 2 ).