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[{1,3,5‐(CH 3 ) 3 H 3 C 6 } 6 Tl 4 ][GaBr 4 ] 4 — Synthesis and Structure of a Mixed Mono‐ and Bis(arene)thallium Complex
Author(s) -
Schmidbaur Hubert,
Bublak Wolfgang,
Riede Jürgen,
Müller Gerhard
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504141
Subject(s) - mesitylene , chemistry , ion , molecule , analytical chemistry (journal) , benzene , organic chemistry , chromatography
A tetrameric Tl 4 [GaBr 4 ] 4 skeletal framework, whose Tl ⊕ ions are alternately coordinated by one or two mesitylene molecules, is present in the title compound. It is formed from Tl[GaBr 4 ] and mesitylene and is the first complex containing both mono‐ and bis(arene)thallium units to be characterized by X‐ray analysis.