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An electrode contact–related mechanism for the operational instability of organic electronic devices is proposed and confirmed via observation of a water‐induced change in charge‐injection barrier heights at the electrode/organic‐semiconductor interfaces. Water molecules in air penetrate into the organic crystal via diffusion, and an external electric field orients the electric dipole of the water molecules at the electrode surfaces, leading to dipolar switching of the charge‐injection barrier height. As a result of the switching, current–voltage curves of two‐terminal Au–rubrene–Au devices change from symmetric to asymmetric, showing diode‐like rectification and reversible switching of the diode polarity. The device shows the highest current switching ratio of 267 for the switching voltage of 3 V, corresponding to an electrode work function change of >144 meV. The mechanism proposed herein will be important especially for short‐channel organic devices, which are indispensable for applications such as organic integrated circuits.

Dipolar Switching of Charge‐Injection Barriers at Electrode/Semiconductor Interfaces as a Mechanism for Water‐Induced Instabilities of Organic Devices