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The complex structure of the Salvinia molesta  is investigated via rare event molecular dynamics simulations. Results show that a hydrophilic/hydrophobic patterning together with a re‐entrant geo­metry control the free energy barriers for bubble nucleation and for the Cassie–Wenzel transition. This natural paradigm is translated into simple macroscopic design criteria for engineering robust superhydrophobicity in submerged applications.

Unraveling the Salvinia Paradox: Design Principles for Submerged Superhydrophobicity