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Using flexible aliphatic chains  to link conjugated molecular semiconductors affords a polymeric material that possesses defined conjugated segments but extended covalent connectivity, which enhances crystallinity and thermal stability in field‐effect transistors and bulk heterojunction solar‐cell devices when used as an additive.

Enhancing the Thermal Stability of Solution‐Processed Small‐Molecule Semiconductor Thin Films Using a Flexible Linker Approach