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The popular dual electronic and structural transitions in VO 2   are explored using X‐ray absorption spectromicroscopy with high spatial and spectral resolutions. It is found that during both heating and cooling, the electronic transition always precedes the structural Peierls transition. Between the two transitions, there are intermediate states that are spectrally isolated here.

Sequential Electronic and Structural Transitions in VO 2 Observed Using X‐ray Absorption Spectromicroscopy