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Though extensively studied since the emergence of zincblende cubic A(B,C)semiconductor alloys (zb-SCA) in the sixties, the phonon mode behavior ofGa(As,P) remains a subject of debate to this day. Recently Zollner andco-authors reported on a thorough far-infrared (IR) ellipsometry study of thevibrational spectra of Ga(As,P) spanning the composition domain. They suggestthat their experimental data are better described by the cluster model than byour percolation model. On the basis of Zollner experimental data, kindly madeavailable to us, we show that the percolation model basically applies toGa(As,P), contrary to the authors original allusion.

Comment on Infrared dielectric function of Ga(As,P) semiconductor alloys near the reststrahlen bands (Applied Physics Letters 123, 172102, 2023)