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Concentric microtubes of $\beta$-cyclodextrin and SDS grow from the outsidein and melt from the inside out, we observe using in situ small angle X-rayscattering. We find that the conformation of the crystalline bilayer affectsthe saturation concentration, providing an example of a phenomenon we callconformational freezing point depression. We propose a model based on freezingpoint depression, well known from undergraduate physics, and use it to explainthe energetics of this hierarchical system, and giving access to materialproperties without free parameters.

Microtube self-assembly leads to conformational freezing point depression