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The investigation of the processes of mineral deposit formation and theirhistory is a fundamental task. Solving this task can increase mining efficiencyand make a significant contribution to understanding the formation of theEarth's crust. The main approach to solving this task is determining the valuesof thermodynamic functions for phases present in deposits. One of the mostpromising and flexible methods for studying thermodynamic properties is the EMFmethod. This article describes the basic principles of the EMF method andprovides all possible interpretations of the obtained results. It has also beendemonstrated that direct EMF measurements can determine the composition of asolid solution or alloy in a multicomponent system if its EMF dependencies areknown. Based on this fact, it can be concluded that any alloy or solid solutionin a multi-phase association, which undergoes composition changes withtemperature and can be quenched, can be used as a geothermometer orgeobarometer.

Theoretical demonstration of the possibility of using binary alloys or solid solutions in ternary systems as geothermometers