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Eutectic NiTiO$_3$-TiO$_2$ samples and their H$_2$ reduced Ni-TiO$_2$samples, where high aspect ratio TiO$_2$ nanostructures are axially decoratedwith nodular Ni globules, are thoroughly explored to understand their effect inphoto-response. We show that by employing this novel eutectic architecture,effectively exploiting the nano-structuring process along with the chosenmaterial properties, the overall efficiency of the ensuing photoactive deviceis improved. We also show the competing photo-driven and photothermal-drivencarrier mechanisms to define the total photo-response of the system.Additionally, the ability to function self-powered poses this approach as apotential strategy for achieving efficient photodetectors.

Anomalous Photoresponse in a Reduced Metal-Semiconductor Hybrid of Nickel and Titanium Oxide