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Magnetic two-dimensional (2D) semiconductors have attracted a lot ofattention because modern preparation techniques are capable of providing singlecrystal films of these materials with precise control of thickness down to thesingle-layer limit. It opens up a way to study rich variety of electronic andmagnetic phenomena with promising routes towards potential applications. Wehave investigated the initial stages of epitaxial growth of the magnetic vander Waals semiconductor FeBr\textsubscript{2} on a single-crystal Au(111)substrate by means of low-temperature scanning tunneling microscopy, low-energyelectron diffraction, x-ray photoemission spectroscopy, low-energy electronemission microscopy and x-ray photoemission electron microscopy. Magneticproperties of the one- and two-layer thick films were measured via x-rayabsorption spectroscopy/x-ray magnetic circular dichroism. Our findings show astriking difference in the magnetic behaviour of the single layer ofFeBr\textsubscript{2} and its bulk counterpart, which can be attributed to themodifications in the crystal structure due to the interaction with thesubstrate.

Epitaxial monolayers of magnetic 2D semiconductor FeBr$_{2}$ grown on Au(111)