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The comment gives principal arguments proving that the claims given in thetitle of the commented paper and some its conclusions have to be wrong forprincipal reasons. An example illustrating the arguments is provided viaatomistic simulation.

Comment on "Extension of Rietveld Refinement for Benchtop Powder XRD  Analysis of Ultrasmall Supported Nanoparticles" by J. Lipp et al. (Chem.  Mater. 2022, 34, 18, 8091-8111)