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Landau - de Gennes mean field model predicts the discontinuous transition forthe Isotropic - Nematic transition, associated with uniaxial and quadrupolarorder parameter in three dimensions. This report shows pressure-relateddielectric studies for rod-like nematogenic pentylcyanobiphenyl (5CB) and itsnanocolloids with BaTiO3 nanoparticles. The scan of dielectric constantrevealed the continuous I-N transition in a compressed nanocolloid with a tinyamount of nanoparticles (x=0.1%). For the nematic phase in 5CB and its x=1%nanocolloid the enormous values of dielectric constant and the bending-typelong-range pretransitional behavior were detected. The 'shaping' influence ofpretransitional fluctuations was also detected for the ionic-relatedcontribution to dielectric permittivity in the isotropic phase. For thehigh-frequency relaxation domain, this impact was tested for the primaryrelaxation time and the translational-orientaional decoupling.

Continuous Isotropic-Nematic transition in compressed rod-like based nanocolloid